Hi Chris,
Thank you for sharing your question. It seems like the app really wants to find the settings automatically and sync everything to the Microsoft cloud, so it ignores what you put in.
Basically, Outlook seems to be holding onto old settings for your account. Once it syncs to the cloud, you can't change the IMAP and SMTP stuff.
Here's what you can try
Close Outlook and delete the account that's giving you trouble.
Wipe out the cached account info by resetting the New Outlook app. Go to Windows Settings, then Apps, find New Outlook, hit Advanced options, and then Reset. This will not delete server emails, but it will delete the stored settings.
Open Outlook again and add the account again. If it still tries to automatically find the settings, switch back to the old Outlook for a bit. Set up your account there with the right server settings, then switch back to the new version if you want. Some people say this works.
If the new Outlook app still isn't letting you fix the settings, you might want to just go back to the classic Outlook or try a different email program that lets you control the IMAP/SMTP settings. The new Outlook doesn't really let you set up the server manually for non-Microsoft email, and it overrides any changes you try to make after it's saved its own settings.
I hope this helps.
Best Regards,
Noel