It is not possible to add a second OneDrive account directly to your Microsoft 365 account. However, you can use multiple OneDrive accounts by signing in and out of different accounts in the OneDrive app or web interface. This allows you to share data with others, including non-family members, by sharing specific files or folders from each account as needed. You can also create a team site in SharePoint for ongoing collaboration with others if that suits your needs better.
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