Dear Joe Grover,
Based on your description, you've already ruled out most common causes—including login script replication, Group Policy, startup tasks, and registry entries. Given that the F: drive mapping continues to reappear even after manual disconnection and reboot, we recommend investigating the following additional areas:
Roaming Profile or Cached Credentials If the user has a roaming profile or previously cached credentials, remnants of the old mapping may be reapplying during session initialization. Try logging the user into a clean test machine to confirm whether the issue is profile-specific.
Mapped Drive Persistence via Credential Manager Check Control Panel > Credential Manager for any saved network credentials that may be triggering automatic reconnection to the legacy share.
Logon Script Execution via Alternate Mechanism Use gpresult /h result.html or rsop.msc to confirm that no other Group Policy Object is applying a drive mapping outside of the expected login script.
Registry Tattooing Occasionally, drive mappings can be "tattooed" into the registry. Inspect HKCU\Network\F and HKLM\SYSTEM\CurrentControlSet\Services\LanmanWorkstation\Parameters for any residual entries.
DFS Namespace or Alias Mapping If the original share was part of a DFS namespace or alias, the mapping may be resolving through an alternate path. Confirm that no DFS links are redirecting the F: drive.
We also recommend temporarily assigning the user a blank login script and monitoring behavior across multiple machines. If the issue persists only on one device, a local profile reset may be necessary.
You can find a similar case and community discussion on Microsoft Q&A, which may offer additional insights.
If the above response helps answer your question, remember to "Accept Answer" so that others in the community facing similar issues can easily find the solution. Your contribution is highly appreciated.
Best regards,
Harry Phan